Containing Dopant Salt Patents (Class 252/299.2)
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Compound, liquid crystal composition, cured product, optically anisotropic body, and reflective film
Patent number: 11905449Abstract: A compound having an excellent rate of change in HTP caused by exposure is achieved and is represented by General Formula (1). In addition, a composition is formed of the compound, and a cured product, an optically anisotropic body, or a reflective film is obtained by curing the composition.Type: GrantFiled: August 27, 2021Date of Patent: February 20, 2024Assignee: FUJIFILM CorporationInventors: Yuko Suzuki, Keisuke Kodama -
Patent number: 11505745Abstract: A use of zwitterionic compound in preparation of dynamic-scattering-mode-based liquid crystal material. A liquid crystal material is also described. Such material contains liquid crystal and dopant, and the dopant is zwitterionic compound. A liquid crystal electro-optical device comprising such liquid crystal compound and the use of such optical device are also described. Zwitterionic compound is used as dopant to induce a stable dynamic scattering mode in liquid crystals.Type: GrantFiled: December 28, 2018Date of Patent: November 22, 2022Assignees: SHENZHEN GUOHUA OPTOELECTRONICS CO., LTD., ACADEMY OF SHENZHEN GUOHUA OPTOELECTRONICSInventors: Guofu Zhou, Yuanyuan Zhan, Danqing Liu, Albertus Petrus Henricus Johannes Schenning, Dirk Jan Broer
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Patent number: 10001703Abstract: The invention relates to a photopolymer formulation comprising a component reactive toward isocyanates, a polyisocyanate component, a writing monomer and a photoinitiator containing at least one dye and a coinitiator, characterized in that the coinitiator contains at least one substance of the formula (Ia) The invention further provides a process for preparing the specific coinitiators and the coinitiators obtainable by this process, and additionally a process for producing a holographic medium using the specific coinitiators, and a holographic medium obtainable using the inventive photopolymer formulation. The invention further relates to a laminate structure comprising an inventive holographic medium and likewise specific borates suitable as coinitiators.Type: GrantFiled: October 13, 2014Date of Patent: June 19, 2018Assignee: Covestro Deutschland AGInventors: Horst Berneth, Thomas Rölle, Friedrich-Karl Bruder, Dennis Hönel, Marc-Stephan Weiser, Thomas Fäcke, Rainer Hagen, Günther Walze
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Patent number: 9737854Abstract: In a process for the purification of a liquid-crystal mixture (7), the liquid-crystal mixture (7) is passed through a first electrodialysis cell (2) and a concentrate solution (14) is passed through a second electrodialysis cell (8) which is adjacent to the first electrodialysis cell (2) and is separated by an ion-exchanger membrane (9), and an electric field transverse to a direction of passage of the liquid-crystal mixture (7) through the first electrodialysis cell (2) is generated with the aid of an anode/cathode arrangement (15, 16) arranged outside the electrodialysis cells (2, 8) so that ionized constituents of the liquid-crystal mixture (7) are discharged at the ion-exchanger membrane (9) and removed from the liquid-crystal mixture (7).Type: GrantFiled: December 16, 2014Date of Patent: August 22, 2017Assignee: MERCK PATENT GMBHInventor: Uwe Kaetzel
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Patent number: 9315603Abstract: An object is to provide a polymerizable compound having high polymerization reactivity, a high conversion ratio and high solubility in a liquid crystal composition, a polymerizable composition containing the compound, a liquid crystal composite prepared from the composition, and a liquid crystal display device having the composite. A solution is a polymerizable compound represented by formula (1). In the formula, for example, P1 and P2 are —OCO—(CH3)C?CH2; S1 and S2 are a single bond; ring A1, ring A2 and ring A3 are 1,4-phenylene; Z1, Z2 and Z3 are a single bond; two of G is —CH? or —N?; and a is 0 or 1.Type: GrantFiled: July 31, 2014Date of Patent: April 19, 2016Assignees: JNC CORPORATION, JNC PETROCHEMICAL CORPORATIONInventors: Yasuyuki Gotoh, Teizi Satou
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Patent number: 9005478Abstract: A liquid crystal composition comprising a chiral dopant compound represented by the following structure (Structure 1): wherein: R1 and R2 are independently hydrogen, —(C?O)R9, —(C?O)R10, alkyl, aryl, alkaryl, alkenyl, cycloalkyl, alkoxyaryl, or heterocyclic all either substituted or unsubstituted, or combine to form a carbocyclic or heterocyclic ring; R3 is hydrogen, halogen, cyano, alkoxy, NHCOR9, NHSO2R9, COOR9, OCOR9, aryl, alkyl, alkenyl, cycloalkyl, or heterocyclic all either substituted or unsubstituted; R4 is hydrogen, alkyl, aryl, alkenyl, cycloalkyl, or heterocyclic all either substituted or unsubstituted; R5, R6, R7, and R8 are independently hydrogen, halogen, cyano, alkoxy, NHCOR9, NHSO2R9, COOR9, OCOR9, aryl, alkyl, alkenyl, cycloalkyl, alkoxyaryl or heterocyclic all either substituted or unsubstituted, or combine with each other, or R5 can combine with R4 to form a carbocyclic or heterocyclic ring; R9 and R10 are independently alkyl, alkoxy, aryl, naphthyl, styryl, alkenyl, cycloalkyl, alkoType: GrantFiled: January 6, 2014Date of Patent: April 14, 2015Assignees: Kent Displays Incorporated, Kent State UniversityInventors: Donald R. Diehl, Erica N. Montbach
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Patent number: 8999195Abstract: A liquid crystal smectic A composition that can be switched by the application of different electric fields across it between a first stable state (left hand block in FIG. 4) and at least one second stable state (right hand block in FIG. 4) in which the composition is less ordered than in the first state. The radiation transmission properties of the first and second states are different.Type: GrantFiled: January 9, 2012Date of Patent: April 7, 2015Assignee: Cambridge Enterprise LimitedInventors: Daping Chu, Huan Xu, William Alden Crossland, Anthony Bernard Davey
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Patent number: 8956548Abstract: The present, invention relates to liquid crystal compositions having a smectic A structure for use in an optical device in which the composition is sandwiched between a pair of electrodes (12-15). In essence the composition includes a siloxane oligomer (component (a)) which may be seen to construct a layered SmA system of particular spacing and “strength”. Within this structure a low molar mass nematic mesogen (component (c)) is provided that may be considered to be that of a “plasticiser” which moderates the layer “strength”, while simultaneously providing tuneability to the properties of the composition, e.g. its refractive index or dielectric anisotropy. The addition of a side chain liquid crystal polysiloxane (component (d)) allows such systems to be further moderated since they can be considered as binding together the la>¾rs, both within a given layer and between layers.Type: GrantFiled: March 15, 2011Date of Patent: February 17, 2015Assignees: Dow Corning Corporation, Cambridge Enterprise LimitedInventors: Terry Victor Clapp, William Alden Crossland, Anthony Bernard Davey, Martin Grasmann, Jonathan Paul Hannington, Russell Keith King, Mikhael Pivnenko, Steven Robson, Huan Xu
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Patent number: 8951438Abstract: A chiral liquid crystal precursor composition which comprises at least one salt that changes a position of the selective reflection band exhibited by the composition in a cured state compared to the position of a selective reflection band exhibited by a composition in the cured state that does not contain the at least one salt. This abstract is neither intended to define the invention disclosed in this specification nor intended to limit the scope of the invention in any way.Type: GrantFiled: December 7, 2011Date of Patent: February 10, 2015Assignee: Sicpa Hòlding SAInventors: Andrea Callegari, Tristan Jauzein
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Patent number: 8828507Abstract: Provided are phase-separating polymer systems including a cured polymeric liquid crystal matrix phase and a guest phase including at least one photoactive material where the guest phase separates from the matrix phase during the curing process. Optical elements, including ophthalmic elements and other articles of manufacture including the phase-separating polymer systems are also disclosed. Methods of forming a liquid crystal phase-separating photoactive polymer system are also described.Type: GrantFiled: February 8, 2011Date of Patent: September 9, 2014Assignee: Transitions Optical, Inc.Inventors: Meng He, Anil Kumar, Peter C. Foller, Chenguang Li, Ruisong Xu, Jiping Shao
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Patent number: 8709281Abstract: A liquid crystal composition comprising a chiral dopant compound represented by the following structure (Structure 1): wherein: R1 and R2 are independently hydrogen, —(C?O)R9, —(C?O)R10, alkyl, aryl, alkaryl, alkenyl, cycloalkyl, alkoxyaryl, or heterocyclic all either substituted or unsubstituted, or combine to form a carbocyclic or heterocyclic ring; and R3-R9 are as described in the disclosure. Also featured are liquid crystal compositions comprising a chiral dopant compound represented by any of Structure 2-4 as described in the disclosure.Type: GrantFiled: August 24, 2012Date of Patent: April 29, 2014Assignee: Kent State UniversityInventors: Donald R. Diehl, Erica N. Montbach
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Publication number: 20130342773Abstract: A liquid crystal smectic A composition that can be switched by the application of different electric fields across it between a first stable state (left hand block in FIG. 4) and at least one second stable state (right hand block in FIG. 4) in which the composition is less ordered than in the first state. The radiation transmission properties of the first and second states are different.Type: ApplicationFiled: January 9, 2012Publication date: December 26, 2013Inventors: Daping Chu, Huan Xu, William Alden Crossland, Anthony Bernard Davey
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Publication number: 20130155340Abstract: The present, invention relates to liquid crystal compositions having a smectic A structure for use in an optical device in which the composition is sandwiched between a pair of electrodes (12-15). In essence the composition includes a siloxane oligomer (component (a)) which may be seen to construct a layered SmA system of particular spacing and “strength”. Within this structure a low molar mass nematic mesogen (component (c)) is provided that may be considered to be that of a “plasticiser” which moderates the layer “strength”, while simultaneously providing tuneability to the properties of the composition, e.g. its refractive index or dielectric anisotropy. The addition of a side chain liquid crystal polysiloxane (component (d)) allows such systems to be further moderated since they can be considered as binding together the la>¾rs, both within a given layer and between layers.Type: ApplicationFiled: March 15, 2011Publication date: June 20, 2013Inventors: Terry Victor Clapp, William Alden Crossland, Anthony Bernard Davey, Martin Grasmann, Jonathan Paul Hannington, Russell Keith King, Mikhael Pivnenko, Steven Robson, Huan Xu
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Patent number: 8287969Abstract: An isosorbide derivative of Formula (I) is provided. In Formula (I), Z is —CH2—CH2—, —CH?CH—, —C?C—, —CH2—O—, —CH2—S—, —CH?N—O—, —CO—O—, —CO—S—, single bond, -ph-, —CO—O-ph- or —CO—O-ph-CO—O—, and ph represents benzene, R1 and R2 are, independently, C1-25 alkyl, —CN, —NCS, —CX3 or —OCX3, and X represents halogen, and m and n are, independently, 0, 1 or 2. The invention also provides a liquid crystal display including the isosorbide derivative.Type: GrantFiled: December 15, 2010Date of Patent: October 16, 2012Assignee: Industrial Technology Research InstituteInventors: Chun-Ming Wu, Kevin Lin, Shih-Hsien Liu, Chih-Lung Chin, An-Cheng Chen, Kung-Lung Cheng, Chien-Hsien Cheng
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Publication number: 20120141745Abstract: A chiral liquid crystal precursor composition which comprises at least one salt that changes a position of the selective reflection band exhibited by the composition in a cured state compared to the position of a selective reflection band exhibited by a composition in the cured state that does not contain the at least one salt. This abstract is neither intended to define the invention disclosed in this specification nor intended to limit the scope of the invention in any way.Type: ApplicationFiled: December 7, 2011Publication date: June 7, 2012Applicant: SICPA HOLDING SAInventors: Andrea CALLEGARI, Tristan JAUZEIN
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Publication number: 20120141697Abstract: A substrate having thereon a marking or layer comprising a cured chiral liquid crystal precursor composition which comprises at least one salt that changes the position of a selective reflection band exhibited by the cured composition compared to the position of a selective reflection band exhibited by a cured composition that does not contain the at least one salt. A modifying resin made from one or more polymerizable monomers is disposed between the substrate and the marking or layer and changes the position of the selective reflection band exhibited by the cured precursor composition comprising the at least one salt on the substrate in the one or more areas. This abstract is neither intended to define the invention disclosed in this specification nor intended to limit the scope of the invention in any way.Type: ApplicationFiled: December 7, 2011Publication date: June 7, 2012Applicant: SICPA HOLDING SAInventors: Andrea CALLEGARI, Tristan JAUZEIN
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Patent number: 8114316Abstract: The invention relates to novel mono-, oligo and polymers of thieno[2,3-b]thiophene, to their use as semiconductors or charge transport materials, in optical, electro-optical or electronic devices like LCDs, optical films, FETs or OFETs for TFT-LCDs and IC devices such as RFID tags, electroluminescent devices in flat panel displays or photovoltaic or sensor devices, and further relates to a FET, light emitting device or ID tag comprising the novel polymers.Type: GrantFiled: July 23, 2005Date of Patent: February 14, 2012Assignee: Merck Patent GmbHInventors: Martin Heeney, Clare Bailey, Steven Tierney, Iain McCulloch
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Patent number: 8025938Abstract: The present invention relates to photo-tunable dopant compositions comprising a photo-reactive chiral compound capable of undergoing a photochemical reaction resulting in the loss of chirality, and a triplet sensitizer. The present invention also relates to a display comprising a substrate, a liquid crystalline layer thereon, wherein the liquid crystalline layer comprises a nematic host, at least one chiral dopant, a photo-reacted compound, and a triplet sensitizer, and at least one transparent conductive layer. The present invention also relates to a method of tuning a cholesteric liquid crystal material comprising providing at least one mesogenic compound, at least one triplet sensitizer, and at least one photo-reactive chiral compound; combining the at least one mesogenic compound, at least one triplet sensitizer, and at least one photo-reactive chiral compound to form a mixture; and irradiating the mixture for a period of time.Type: GrantFiled: November 20, 2009Date of Patent: September 27, 2011Assignee: Industrial Technology Research InstituteInventors: Deepak Shukla, Krishnan Chari
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Patent number: 8003005Abstract: Various non-limiting embodiments disclosed herein provide phase-separating polymer systems including a cured polymeric liquid crystal matrix phase and a guest phase including at least one photoactive material where the guest phase separates from the matrix phase during the curing process. Optical elements, including ophthalmic elements and other articles of manufacture including the phase-separating polymer systems are also disclosed. Methods of forming a liquid crystal phase-separating photoactive polymer system are also described.Type: GrantFiled: December 5, 2008Date of Patent: August 23, 2011Assignee: Transitions Optical, Inc.Inventors: Meng He, Anil Kumar, Peter C. Foller, Chenguang Li, Ruisong Xu, Jiping Shao
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Publication number: 20110135853Abstract: A liquid crystal polymer marking is obtainable by a process that comprises applying a chiral liquid crystal precursor composition onto a substrate, heating the composition to a chiral liquid crystal state, applying to at least one area of the precursor composition a modifying composition, if necessary, heating the at least one area to bring same to a modified liquid crystal state, and subsequently curing and/or polymerizing the resultant product. This abstract is neither intended to define the invention disclosed in this specification nor intended to limit the scope of the invention in any way.Type: ApplicationFiled: May 19, 2010Publication date: June 9, 2011Applicant: SICPA HOLDING S.A.Inventors: Thomas TILLER, Frédéric GREMAUD, Andrea CALLEGARI, Olivier ROZUMEK, Brahim KERKAR
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Patent number: 7919008Abstract: Disclosed are a silicon-containing compound, a liquid crystal composition comprising the same compound, and a liquid crystal display device comprising a liquid crystal layer prepared from the liquid crystal composition. The silicon-containing compound, which forms the liquid crystal composition, has low viscosity and high negative (?) dielectric anisotropy. Therefore, it is possible to provide a liquid crystal display device, which has a fast response time and can be driven at a low voltage.Type: GrantFiled: January 12, 2006Date of Patent: April 5, 2011Assignee: LG Chem, Ltd.Inventors: Jae Ho Cheong, Min Jin Ko, Dae Ho Kang, Ki Youl Lee, Youn Bong Kim
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Patent number: 7914700Abstract: The invention relates to compounds of formula (I): wherein R1 and R2 are each independently selected from the group: H, F, Cl and CH3; n1 and n2 are each independently integers 3 to 20; q and r are each independently integers 0, 1 or 2, with the proviso that q+r is ?1; D is a divalent chiral radical selected from the group: wherein R3 is a C1 to C6 straight or branched chain alkyl group; and each B1 and B2 is a divalent radical independently selected from the group: R4-substituted-1,4-phenyl, wherein R4 is H, —CH3 or —OCH3; 2,6-naphthyl; and 4,4?-biphenyl; with the provisos that when q+r=3, at least one of B1 and B2 is R4-substituted-1,4-phenyl; and when q+r=4, at least two of B1 and B2 are R4-substituted-1,4-phenyl. The invention further relates to liquid crystal compositions comprising compounds of formula (I) and polymer networks derived from the polymerization of the liquid crystal compositions.Type: GrantFiled: March 30, 2007Date of Patent: March 29, 2011Assignee: E. I. du Pont de Nemours and CompanyInventors: Marc B. Goldfinger, Jose Manuel Rodriguez-Parada, Lee A. Silverman, Kai Qi
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Patent number: 7857991Abstract: Provided are a dichroic dye composition in which a solubility of the dichroic dye with respect to liquid-crystal is sufficiently high and a wavelength dispersion of absorbance is small in a wide wavelength range, and a black guest-host liquid-crystal composition indicating high order parameters using such a dichroic dye composition and a liquid-crystal element having high contrast. The dichroic dye composition includes at least one dichroic dye selected from Group (I) shown below, at least one dichroic dye selected from Group (II) shown below, and at least one dichroic dye selected from Group (III) shown below.Type: GrantFiled: January 17, 2008Date of Patent: December 28, 2010Assignee: Sony CorporationInventors: Yasushi Shiga, Yuki Tanaka, Mio Ishida, Kazuhiro Tanaka, Keita Kaifu, Yukihiro Sano
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Publication number: 20100289999Abstract: The invention provides a liquid crystal (LC) composition, a LC device such as a liquid crystal display and a phase modulator, and a method thereof. The liquid crystal composition comprises a liquid crystal and a polymer. The liquid crystal exhibits a macroscopic anisotropic property such as optical property in the absence of the polymer under a condition such as certain temperature. The polymer in the composition stabilizes the liquid crystal so that the liquid crystal exhibits a macroscopic isotropic property under the same condition, and the liquid crystal stabilized by the polymer exhibits the macroscopic anisotropic property when an electrical field is applied thereon. The devices exhibit technical merits such as large viewing angle, fast response time, better contrast ratio, easy manufacturability of large size display with improved dark state, easy manufacturing process with wider temperature region, and polarization-insensitivity of PSI phase modulator, among others.Type: ApplicationFiled: May 13, 2010Publication date: November 18, 2010Inventors: Deng-Ke Yang, Young Cheol Yang, Rui Bao
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Patent number: 7771801Abstract: The invention relates to chiral compounds, methods of their preparation, and to their use in optical, electrooptical, electronic, semiconducting or luminescent components or devices, and in decorative, security, cosmetic or diagnostic applications.Type: GrantFiled: September 20, 2006Date of Patent: August 10, 2010Assignee: Merck Patent GmbHInventor: Louise Diane Farrand
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Patent number: 7771800Abstract: The invention relates to chiral compounds, methods of their preparation, and to their use in optical, electrooptical, electronic, semiconducting or luminescent components or devices, and in decorative, security, cosmetic or diagnostic applications.Type: GrantFiled: September 20, 2006Date of Patent: August 10, 2010Assignee: Merck Patent GmbHInventor: Louise Diane Farrand
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Patent number: 7758772Abstract: The invention refers to a composition comprising a liquid crystal material and an additive, preferably a dopant capable of forming a complex with said LC material, to a liquid crystal cell comprising this composition, uses thereof and to a method of improving the response time of a liquid crystal.Type: GrantFiled: October 7, 2004Date of Patent: July 20, 2010Assignees: Sony Deutschland GmbH, Sony CorporationInventors: Anthony Roberts, Akira Masutani, Akio Yasuda, Bettina Schueller, Shunichi Hashimoto, Eriko Matsui
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Patent number: 7713436Abstract: Doped electrically actuatable (electrically addressable or switchable) polymer flakes have enhanced and controllable electric field induced motion by virtue of doping a polymer material that functions as the base flake matrix with either a distribution of insoluble dopant particles or a dopant material that is completely soluble in the base flake matrix. The base flake matrix may be a polymer liquid crystal material, and the dopants generally have higher dielectric permittivity and/or conductivity than the electrically actuatable polymer base flake matrix. The dopant distribution within the base flake matrix may be either homogeneous or non-homogeneous. In the latter case, the non-homogeneous distribution of dopant provides a dielectric permittivity and/or conductivity gradient within the body of the flakes.Type: GrantFiled: September 19, 2005Date of Patent: May 11, 2010Assignee: The University of RochesterInventors: Anka Trajkovska-Petkoska, Stephen D. Jacobs, Kenneth L. Marshall, Tanya Z. Kosc
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Patent number: 7678292Abstract: An ionic dopant comprising a sulfur or a phosphorus containing anion with a randon cation, for use in a smectic A liquid crystal composition. The cation preferably comprises a quaternary ammonium cation.Type: GrantFiled: September 2, 2003Date of Patent: March 16, 2010Assignee: Polydisplay ASAInventors: Kjetil A. Netland, Maxim V. Mitrokhine, Lorenzo Williams, Kjetil H. Holm, Fiona J. Farrand
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Patent number: 7678880Abstract: A molecular-oriented polymer gel and its cast film obtained by self-assembly of a self-organizable amphiphilic compound and a monomer interacting with the amphiphilic compound, and then polymerizing the monomer, and their production methods.Type: GrantFiled: August 7, 2003Date of Patent: March 16, 2010Assignees: Honda Giken Kogyo Kabushiki KaishaInventors: Nobuo Kimizuka, Kazuhiro Kagawa, Takuya Nakashima
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Publication number: 20090267025Abstract: The instant invention relates to mesogenic systems comprising a) a polymeric component, component A, obtained or obtainable from polymerisation of a precursor comprising one or more mesogenic mono-reactive compounds, one or more di-reactive compounds, which optionally are also mesogenic compounds and optionally a photo-initiator and a low molecular weight component, component B, comprising one or more mono-reactive, mesogenic compounds, one or more mesogenic compounds and one or more chiral dopants, exhibiting a Blue Phase, as well as to the use of these systems in deices and to these devices.Type: ApplicationFiled: November 22, 2005Publication date: October 29, 2009Inventors: Cecile Schott, Patrick John, Adlem Kevin, Farrand Diane Louise, Bernatz Georg, Goetz Achim, Best Peter, Herbert Plach
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Patent number: 7563389Abstract: The present invention relates to photo-tunable dopant compositions comprising a photo-reactive chiral compound capable of undergoing a photochemical reaction resulting in the loss of chirality, and a triplet sensitizer. The present invention also relates to a display comprising a substrate, a liquid crystalline layer thereon, wherein the liquid crystalline layer comprises a nematic host, at least one chiral dopant, a photo-reacted compound, and a triplet sensitizer, and at least one transparent conductive layer. The present invention also relates to a method of tuning a cholesteric liquid crystal material comprising providing at least one mesogenic compound, at least one triplet sensitizer, and at least one photo-reactive chiral compound; combining the at least one mesogenic compound, at least one triplet sensitizer, and at least one photo-reactive chiral compound to form a mixture; and irradiating the mixture for a period of time.Type: GrantFiled: December 10, 2008Date of Patent: July 21, 2009Assignee: Industrial Technology Research InstituteInventors: Deepak Shukla, Krishnan Chari
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Patent number: 7482043Abstract: The present disclosure describes liquid crystal materials comprising a nematic liquid crystal composition and fullerene-containing complex with high-speed electro-optical response. The fullerene-containing complex includes an organic donor and fullerene, where organic donor represents the electro-optical molecule with initial internal donor-acceptor interaction. The present disclosure also includes liquid crystal devices based on the composition mentioned above. The systems and techniques described herein provide a nematic liquid crystal structure sensitized with a fullerene-containing complex. The material provides improved temporal parameters of the NLC electro-optic response under conditions that maintain good contrast of liquid crystal display devices.Type: GrantFiled: October 5, 2006Date of Patent: January 27, 2009Assignees: Samsung Electronics Co., LtdInventor: Natalia Vladimirovna Kamanina
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Patent number: 7470376Abstract: The present invention relates to a phototunable chiral dopant represented by the following structure: wherein: A, B, C and D are independent divalent groups; X and Z are any independently selected substituent; n is an integer and independently varies from 0 to 3; q is an integer and independently varies from 0 to 5; RNG1 and RNG2 independently represent any ring group; m represents an integer independently varying from 0 to 4; p represents an integer independently varying from 1 to 4; Q independently represents a carbon C—RC, or nitrogen, wherein RC is independently hydrogen or any substituent. The invention also relates to the use of the dopant in a liquid crystalline composition and a display containing the same, as well as a material composition comprising an enantiomeric excess of one enantiomer of the compound.Type: GrantFiled: October 29, 2004Date of Patent: December 30, 2008Assignee: Industrial Technology Research InstituteInventors: Thomas R. Welter, Krishnan Chari
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Patent number: 7462297Abstract: The present invention relates to chiral dopants having a laterally alkylated phenyl unit of the general formula I: in which Q*, R, A, Z, V, W, X, Y and n are as defined in claim 1, to the use thereof as components in liquid-crystalline mixtures, and to liquid-crystal and electro-optical display elements which contain the liquid-crystalline mixtures according to the invention.Type: GrantFiled: September 23, 2003Date of Patent: December 9, 2008Assignee: Merck Patent GmbHInventors: Volker Reiffenrath, Michael Heckmeier
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Patent number: 7452482Abstract: The present invention relates to a phototunable chiral dopant represented by the following structure: wherein: A, B, C and D are independent divalent groups; X and Z are any independently selected substituent; n is an integer and independently varies from 0 to 3; q is an integer and independently varies from 0 to 5; RNG1 and RNG2 independently represent any ring group; m represents an integer independently varying from 0 to 4; p represents an integer independently varying from 1 to 4; Q independently represents a carbon C—RC, or nitrogen, wherein RC is independently hydrogen or any substituent. The invention also relates to the use of the dopant in a liquid crystalline composition and a display containing the same, as well as a material composition comprising an enantiomeric excess of one enantiomer of the compound.Type: GrantFiled: December 15, 2004Date of Patent: November 18, 2008Assignee: Industrial Technology Research InstituteInventor: Thomas R. Welter
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Patent number: 7435357Abstract: The invention relates to a polymerised liquid crystal (LC) film comprising at least one photoisomerisable compound and having a pattern of regions with different retardation and/or different orientation of the LC material, to methods of preparing such a film, and to its use as alignment layer, optical retardation film or optical waveguide in liquid crystal displays or other optical or electrooptical components or devices, or for decorative or security applications.Type: GrantFiled: April 2, 2004Date of Patent: October 14, 2008Assignee: Merck Patent GmbHInventors: Richard Harding, Shirley Ann Marden, Ian Victor Edward Hassall, Janice McCreary, Karl Skjonnemand
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Patent number: 7419620Abstract: A mesogenic, crosslinkable mixture comprising at least one polymerisable liquid crystal and at least one polymerisable dichroic dye of the general formula I: wherein A represents a dichroic residue exhibiting at least partial absorption in the visible region >400 nm; n1, n2, n3, n4 signifies 0 or 1 whereby the sum of n1, n2, n3 and n4 is >0, and B1 and B4 represent a group of substructure II wherein the broken line symbolises the linkage to said dichroic residue.Type: GrantFiled: January 28, 2002Date of Patent: September 2, 2008Assignee: Rolic Ltd c/o Rolic Technologies LtdInventors: Richard Buchecker, Zoubair M. Cherkaoui, Thomas Peglow, Franco Moia
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Patent number: 7416683Abstract: The invention relates to a liquid crystal mixed-composition comprising one or more cellulose derivatives and one or more liquid crystal compounds (preferably low-molecular liquid crystal compound) which can be oriented in a specific direction differing from that of the cellulose derivative, wherein the ratio by weight of the both is preferably in a range from 1:9 to 9:1, a retardation film produced using the composition, a circularly or elliptically polarizing film using the retardation film and an image display device provided with a circularly or elliptically polarizing film. The liquid crystal mixed-composition can be easily oriented in a specific direction on a rubbed substrate. If this orientation is fixed, a retardation film can be easily obtained which has such wavelength dispersion characteristics that the same level of retardation can be imparted to each wavelength in a wide visible region.Type: GrantFiled: November 6, 2003Date of Patent: August 26, 2008Assignees: Nippon Kayku Kabushiki Kaisha, Polatechno Co., Ltd.Inventors: Hideyoshi Fujisawa, Kouichi Tanaka
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Patent number: 7416682Abstract: The invention relates to novel photochromic liquid crystal materials which may be used in various electro-optic devices including liquid crystal devices. The materials can be converted into another form on irradiation by light which may make it feasible for them to be addressed by light in electro-optic devices. The materials are based on 5-membered heterocycles.Type: GrantFiled: June 26, 2003Date of Patent: August 26, 2008Assignee: Chi Mei Optoelectronics CorporationInventors: Michael Frigoli, Georg Mehl
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Patent number: 7364671Abstract: A polymerisable mixture that can be applied as a layer, an orientation layer of the mixture, and an optical component, such as a retarder or a liquid crystal display, having a layer of which the mixture is a precursor.Type: GrantFiled: April 26, 2006Date of Patent: April 29, 2008Assignee: Rolic Ltd c/o Rolic Technologies LtdInventors: Martin Schadt, Hubert Seiberle
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Patent number: 7294370Abstract: An aligned film comprises a dried mixture of a lyotropic chromonic liquid crystal material and a dopant selected from the group consisting of dyes having a molecular weight within one order of magnitude of the liquid crystal material and block co-polymers. An example of an aligned film may be transparent to visible light but not transparent to polarized light in the ultraviolet and/or infra-red portions of the electromagnetic spectrum. A method of making an aligned lyotropic chromonic liquid crystal-based film comprises providing a mixture of a lyotropic chromonic liquid crystal material and a dopant in a solvent for the liquid crystal material, applying the mixture to a substrate, and removing the solvent to produce an aligned lyotropic chromonic liquid crystal-based film.Type: GrantFiled: August 17, 2004Date of Patent: November 13, 2007Assignee: Kent State UniversityInventors: Oleg Lavrentovich, Tod Schneider, Andrii Golovin, Jong-Chan Lee
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Publication number: 20070228325Abstract: The chiral agent used for liquid crystal according to the present invention comprises a phosphoric acid amide represented by General Formula (1) below: in General Formula (1), the binaphthyl structure has an axial asymmetry of either (R) or (S); R1 and R2 may be identical or different and each represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an alkenyl group, an alkynyl group or an alkoxy group; R3 and R4 may be identical or different and each represents a hydrogen atom, an alkyl group or an aryl group.Type: ApplicationFiled: March 30, 2007Publication date: October 4, 2007Applicant: FUJIFILM CorporationInventor: Masatoshi Yumoto
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Patent number: 7258902Abstract: The invention relates to chiral 3,4-dihydro-2H-pyran compounds and diastereomers thereof, and to the use of these compounds as chiral dopants for liquid-crystalline systems. The invention furthermore relates to non-polymerizable or polymerizable liquid-crystalline compositions which comprise at least one chiral 3,4-dihydro-2H-pyran compound according to the invention, to the use of these non-polymerizable or polymerizable liquid-crystalline compositions for the production of optical components, to the use of the polymerizable liquid-crystalline compositions for printing or coating substrates, for the preparation or production of dispersions and emulsions, films or pigments and optical components of this type, printed or coated substrates, dispersions and emulsions, films and pigments.Type: GrantFiled: June 30, 2003Date of Patent: August 21, 2007Assignee: BASF AktiengesellschaftInventors: Robert Parker, Frank Prechtl, Sylke Haremza, Frank Meyer, Volkmar Vill, Gunnar Gesekus
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Patent number: 7166238Abstract: A novel liquid-crystalline ionic conductor, which is useful in the electric, electronic, chemical and bioengineering fields, as an anisotropic reaction solvent, ionic conductor, electric field-responsible conductor or the like, and a method for producing the same, is provided. The liquid-crystalline ionic conductor is obtained by mixing an organic molten salt with a-liquid-crystalline organic molecule or a liquid-crystalline inorganic molecule, which comprises a moiety miscible to the organic molten salt and a moiety that shows liquid-crystalline orientation, thereby forming a liquid-crystalline ionic conductor, wherein the organic molten salt is assembled to the liquid-crystalline molecule.Type: GrantFiled: September 14, 2005Date of Patent: January 23, 2007Assignee: Japan Science and Technology CorporationInventors: Takashi Kato, Kiyoshi Kanie, Masafumi Yoshio, Hiroyuki Ohno, Masahiro Yoshizawa
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Patent number: 7150900Abstract: The invention relates to a class of compounds useful as chiral dopants, which compounds are available in both enantiomeric forms, in liquid-crystal formulations. Such formulations are advantageous in displays and various other products.Type: GrantFiled: December 16, 2003Date of Patent: December 19, 2006Assignee: Eastman Kodak CompanyInventor: Thomas R. Welter
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Patent number: 7122227Abstract: The invention relates to chiral photoisomerizable compounds of formula (I) wherein X1, X2, X3, X4, X5 and X6 have the meanings given in claim 1, to liquid crystalline mixtures and polymers containing them, and to the use of chiral photoisomerizable compounds, liquid crystalline mixtures and polymers containing them in optical and electrooptical devices like liquid crystal displays or projection systems, in optical elements like polarizers, retardation films, compensators, color filters or holographic elements, in liquid crystal pigments and colored films or coatings for decorative or security applications, cosmetic and pharmaceutical compositions, in nonlinear optics and optical information storage.Type: GrantFiled: September 21, 2001Date of Patent: October 17, 2006Assignee: Merck Patent GesellschaftInventors: Julian Vaughn-Spickers, Simon Greenfield, Ian Victor Edward Hassall, Christopher Dunn, Richard Harding, Tony Jenkins, Alison May
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Patent number: 7097888Abstract: Disclosed is a multilayer film comprising a substrate bearing an aligned liquid crystal layer wherein the aligned liquid crystal layer contains an azolium salt represented by formula (I): wherein the subscripts represent the ring positions and each X is independently N or C—R; each Z is independently N, N—R, C—(R)(R), O, S, SO2, SO, C?O, C?S, or C?NR; each R group is independently hydrogen or a substituent; and Y is a charge balancing anion, which may be a separate moiety or part of an X, Z, or R; provided two or more X, Z and R groups may form a ring; provided the salt may be part of an oligomer or polymer. Such a film provides a predetermined increase in pre-tilt angle for use in liquid crystal devices.Type: GrantFiled: December 15, 2003Date of Patent: August 29, 2006Assignee: Eastman Kodak CompanyInventors: Deepak Shukla, Thomas R. Welter, James F. Elman, Samir Y. Farid
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Patent number: 7052743Abstract: The invention relates to a novel class of compounds useful as chiral dopants, which compounds are available in both enantiomeric forms. Another aspect of the invention relates to such compounds having a enantiomeric excess of one enantiomeric form, which are useful in liquid crystal formulations. Such formulations are advantageous in displays and various other products.Type: GrantFiled: August 29, 2003Date of Patent: May 30, 2006Assignee: Eastman Kodak CompanyInventors: Thomas R. Welter, Krishnan Chari
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Patent number: 7014891Abstract: The present invention relates to a method of improving the response times and bulk on-state alignments of negative-type liquid crystals by providing a liquid crystal material that comprises at least one negative-type mesogen comprising at least one soluble, dipolar dopant.Type: GrantFiled: October 21, 2003Date of Patent: March 21, 2006Assignees: Sony International (Europe) GmbH, Sony CorporationInventors: Anthony Roberts, Akira Masutani, Akio Yasuda, Bettina Schüller, Shunichi Hashimoto